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ChemInform Abstract: An Efficient Synthesis of Substituted meta-Halophenols and Their Methyl Ethers: Insight into the Reaction Mechanism.

โœ Scribed by Faiz Ahmed Khan; Sumit Choudhury


Publisher
John Wiley and Sons
Year
2010
Weight
47 KB
Volume
41
Category
Article
ISSN
0931-7597

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PPh3-Catalyzed Reactions of Alkyl Propio
โœ Huimin Liu; QiongMei Zhang; Limin Wang; Xiaofeng Tong ๐Ÿ“‚ Article ๐Ÿ“… 2010 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 283 KB ๐Ÿ‘ 2 views

## Abstract A new PPh~3~โ€catalyzed synthesis of alkyl 2โ€[aryl(tosylimino)methyl]acrylates from propiolate and __N__โ€tosylimine has been developed. Deuteriumโ€labelling experiments show that the reaction mechanism involves several hydrogenโ€transfer processes, which are not the turnoverโ€limiting step