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ChemInform Abstract: An Efficient Stereoselective Synthesis of Stypodiol (IX) and Epistypodiol (XI).

✍ Scribed by A. ABAD; C. AGULLO; M. ARNO; A. C. CUNAT; B. MESEGUER; R. J. ZARAGOZA

Publisher
John Wiley and Sons
Year
2010
Weight
41 KB
Volume
29
Category
Article
ISSN
0931-7597

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✦ Synopsis

An Efficient Stereoselective Synthesis of Stypodiol (IX) and Epistypodiol (XI).

-Key steps in the synthesis of the title compounds are intramolecular Diels-Alder cycloaddition of the triene (II), sonochemical Barbier reaction of the ketone (IV) with the chloride (V), and cyclization of the alcohol (VI). -(ABAD, A.;

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