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ChemInform Abstract: An Efficient and Scalable Synthesis of Substituted Phenanthrenequinones by Intramolecular Friedel—Crafts Reaction of Imidazolides.

✍ Scribed by Naoki Yoshikawa; Austin Doyle; Lushi Tan; Jerry A. Murry; Atsushi Akao; Masashi Kawasaki; Kimihiko Sato

Publisher: John Wiley and Sons
Year: 2008
Weight: 34 KB
Volume: 39
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.200812098

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Substituted Oxocanes by Intramolecular Allylboration Reactions. Entry to an Efficient Synthesis of (+)-Laurencin. -δ5-Oxocenes such as (II) can be generated by an intramolecular aldehyde-allylboration reaction. The key feature of this reaction is that both the aldehyde and the allylboronate functio