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ChemInform Abstract: An Alternative, Highly Stereocontrolled Synthesis of Trisubstituted Cyclopropane Derivatives from Methyl Bis(tributylstannyl)propionate.

✍ Scribed by H. WAKAMATSU; N. ISONO; M. MORI

Publisher: John Wiley and Sons
Year: 2010
Weight: 40 KB
Volume: 29
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.199816079

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✦ Synopsis

An

Alternative, Highly Stereocontrolled Synthesis of Trisubstituted Cyclopropane Derivatives from Methyl Bis(tributylstannyl)propionate.

-A method for the preparation of cyclopropane derivative (XII), a key fragment for the synthesis of ambruticin, is developed and extended to a general synthetic method for the preparation of trisubstituted cyclopropanes starting from known ester (I). -(WAKA-

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