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ChemInform Abstract: An Additional Coordination Group Leads to Extremely Efficient Chiral Iridium Catalysts for Asymmetric Hydrogenation of Ketones.

✍ Scribed by Jian-Hua Xie; Xiao-Yan Liu; Jian-Bo Xie; Li-Xin Wang; Qi-Lin Zhou

Publisher
John Wiley and Sons
Year
2011
Weight
42 KB
Volume
43
Category
Article
ISSN
0931-7597

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✦ Synopsis

Abstract

An efficient chiral iridium catalyst that bears a tridentate spiro Pβ€”Nβ€”N ligand catalyzes the asymmetric hydrogenation of ketones with excellent enantioselectivities and extremely high turnover numbers.

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