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ChemInform Abstract: An ab-initio Study of the Role of Ione Pairs in the Structure and Insulator-Metal Transition in SnO and PbO

✍ Scribed by Jean-Marc Raulot; Gianguido Baldinozzi; Ram Seshadri; Pietro Cortona

Publisher
John Wiley and Sons
Year
2010
Weight
23 KB
Volume
33
Category
Article
ISSN
0931-7597

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It is demonstrated that the upper Hubbard band (UHB) can play an important role in the hopping conductivity; 2D geometry and vicinity of the metal-insulator transition emphasize this role. A simple model for the recently observed metal-insulator transition is suggested. The model starts from the ins