ChemInform Abstract: An ab initio Investigation of Bismuth Hydration.
β Scribed by Cory C. Pye; C. Mahesh Gunasekara; Wolfram W. Rudolph
- Publisher
- John Wiley and Sons
- Year
- 2008
- Weight
- 16 KB
- Volume
- 39
- Category
- Article
- ISSN
- 0931-7597
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The geometries and vibrational frequencies of Li H O , n s 4, 5, 6, 8, 18, 2 n Ε½ . and LiX H O , X s F, Cl, Br, I; n s 3, 6 are calculated at various levels up to MP2r 2 n 6-31qG\*. The solution structure and vibrational spectra with noncoordinating counterions are most consistent with our tetracoo
Acidic solutions containing more than lo-' mol/L H2S became somewhat turbid, presumably due to formation of colloidal sulfur. It was found, however, that this did not significantly influence the results of pulse experiments. a) D .