ChemInform Abstract: Ammonium Ylides for the Diastereoselective Synthesis of Glycidic Amides.
β Scribed by Mario Waser; Richard Herchl; Norbert Mueller
- Publisher
- John Wiley and Sons
- Year
- 2011
- Weight
- 77 KB
- Volume
- 42
- Category
- Article
- ISSN
- 0931-7597
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Mechanism of the Stevens Rearrangement of Ammonium Ylides. -The title rearrangement of the ylide precursor (I) is studied, revealing that the Stevens rearrangement occurs at room temperature. The isomerization to compound (II) is always accompanied by formation of the Sommelet-Hauser rearrangement p