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ChemInform Abstract: Amino Zinc Enolate Carbocyclization Reactions. New Access to Polysubstituted Piperidine Derivatives.

✍ Scribed by E. LORTHIOIS; I. MAREK; J. F. NORMANT

Book ID
101865792
Publisher
John Wiley and Sons
Year
2010
Weight
33 KB
Volume
29
Category
Article
ISSN
0931-7597

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✦ Synopsis

Amino Zinc Enolate Carbocyclization Reactions. New Access to Polysubstituted Piperidine Derivatives.

-The cyclization proceeds with excellent stereoselectivity which is mainly controlled by the substituent at the homoallylic position. Solely, cyclization of the zinc enolate of the amine (VIIb) yields a mixture of diastereomers.

-(LORTHIOIS, E.; MAREK,

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