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ChemInform Abstract: Alkynylation Reactions of gem-Difluorinated 3-Bromo-2-phenylthiopropene: Efficient Synthesis of gem-Difluorinated 2-Phenylthio-1,4-enynes.

✍ Scribed by Ji Hye Hwang; Youn Young Hong; Eun Joon Yang; In Howa Jeong

No coin nor oath required. For personal study only.

✦ Synopsis

The direct alkynylation of the electrophilic gem‐difluorinated propene derivative (I) is achieved via a simple allylic substitution reaction.

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