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ChemInform Abstract: Alkyl, Silyl, and Phosphane Ligands — Classical Ligands in Nonclassical Bonding Modes

✍ Scribed by Pierre Braunstein; Neil M. Boag

Publisher
John Wiley and Sons
Year
2010
Weight
24 KB
Volume
32
Category
Article
ISSN
0931-7597

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Alkyl, silyl, and phosphane ligands are amongst the most familiar and ubiquitous ligands in organometallic and coordination chemistry. The C, Si, and P donor atoms of these ligands are sp(3)-hybridized and the ligands are related to each other by the isolobal analogy: (CR(3))(-)⥈(SiR(3))(-)⥈PR(3). H

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