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ChemInform Abstract: Alkaline-Earth Metal Hydrides as Novel Host Lattices for EuII Luminescence.

✍ Scribed by Nathalie Kunkel; Holger Kohlmann; Adlane Sayede; Michael Springborg

Publisher
John Wiley and Sons
Year
2011
Weight
19 KB
Volume
42
Category
Article
ISSN
0931-7597

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✦ Synopsis

Earth Metal Hydrides as Novel Host Lattices for Eu II Luminescence. -EuxM1-x (M: Ca, Sr, Ba) alloys are synthesized by melting the elements in Nb ampules and subsequently hydrogenated to EuxM1-xH2 (autoclave, 270 bar H2, 500 K). A complete solid solution series exists for EuxSr1-xH2 (x = 0.0-1.0). The compounds crystallize in the orthorhombic space group Pnma with PbCl2 structure (powder XRD). Eu x M 1-x H 2 with a small Eu concentration (x = 0.005) exhibit luminescence with maximum emission wavelengths of 764 nm (M:

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