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ChemInform Abstract: Air-Stable Diaminophosphine Sulfides as Preligands for Nickel-Catalyzed Cross-Couplings of Unactivated Fluoro(hetero)arenes.

✍ Scribed by Lutz Ackermann; Cindy Wechsler; Anant R. Kapdi; Andreas Althammer

Publisher
John Wiley and Sons
Year
2010
Weight
41 KB
Volume
41
Category
Article
ISSN
0931-7597

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Transition-metal-catalyzed cross-coupling reactions [1] of aryl halides or pseudo-halides with organometallic reagents, such as Grignard reagents, organozinc compounds, boronic acids, organostannanes, and organosiloxanes, are powerful tools for the synthesis of the biaryl motif, which is prevalent i