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ChemInform Abstract: Additions of Silyl Enol Ethers to β-Formyl Esters - A Chelate- Controlled Synthesis of the Pheromone (+)-Eldanolide.

✍ Scribed by H. ANGERT; R. CZERWONKA; H.-U. REISSIG

Book ID
112037491
Publisher
John Wiley and Sons
Year
2010
Weight
33 KB
Volume
27
Category
Article
ISSN
0931-7597

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Additions of Silyl Enol Ethers to β-Form
Additions of Silyl Enol Ethers to β-Formyl Esters - a Chelate-controlled Synthesis of the Pheromone (+)-Eldanolide
✍ Angert, Hubert ;Czerwonka, Regina ;Reißig, Hans-Ulrich 📂 Article 📅 2006 🏛 John Wiley and Sons 🌐 English ⚖ 466 KB

## Abstract Chelate‐controlled Mukaiyama reaction of silyl enol ethers 2a, 2b, 2c, and 2d with β‐formylcarboxylate 1 in the presence of TiCl~4~ provided γ‐lactones 3a, 3b, 3c, and 3d in very good yields and with good to excellent __trans__ selectivities. The use of BF~3~, SnCl~4~, and SnBr~4~ as Le

ChemInform Abstract: Mukaiyama Reactions
ChemInform Abstract: Mukaiyama Reactions of a Silyl Enol Ether with Heteroatom-Substituted β-Formyl Esters.
✍ H. ANGERT; R. CZERWONKA; H.-U. REISSIG 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 39 KB 👁 2 views

## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable v