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ChemInform Abstract: Addition Reactions of Allyl Stannanes to an Indolo[2′,3′:3,4]pyrido[1,2-b]isoquinoline Imminium Salt.

✍ Scribed by Paul C. Unangst; Larry D. Bratton; David T. Connor; Bruce D. Roth; J. Ronald Rubin; Bharat K. Trivedi

Publisher
John Wiley and Sons
Year
2001
Weight
35 KB
Volume
32
Category
Article
ISSN
0931-7597

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Addition reactions of allyl stannanes to
Addition reactions of allyl stannanes to an indolo[2′,3′:3,4]pyrido[1,2-b]isoquinoline imminium salt
✍ Paul C. Unangst; Larry D. Bratton; David T. Connor; Bruce D. Roth; J. Ronald Rub 📂 Article 📅 2000 🏛 Journal of Heterocyclic Chemistry 🌐 English ⚖ 513 KB

## Abstract The addition of organometallic reagents to the 13b‐position of the indolo[2′,3′:3,4]pyrido[1,2‐__b__]isoquinoline imminium salt 4 is described. Reaction of **4** with tetraallyl tin in 2‐methoxyethanol gave the allyl adduct **7** in moderate yield. Further elaboration of **7** yielded t