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ChemInform Abstract: Addition of Grignard Reagents to Chiral 1,2-Bisimines: A Diastereoselective Preparation of Unsymmetrical 1,2-Diamines.

โœ Scribed by Sylvain Roland; Pierre Mangeney


Publisher
John Wiley and Sons
Year
2010
Weight
30 KB
Volume
31
Category
Article
ISSN
0931-7597

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Addition of Grignard Reagents to Chiral
โœ Sylvain Roland; Pierre Mangeney ๐Ÿ“‚ Article ๐Ÿ“… 2000 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 290 KB ๐Ÿ‘ 1 views

3,2-b]benzopyran-2-ones / (E)-2-NonenalAsymmetric synthesis / Grignard reactions / Dynamic kinetic resolution / Chiral bisimines / Unsymmetrical 1,2-diamines A diastereoselective synthesis of tert-butyl-1,2-diamines has been developed from the addition of tert-butylmagnesium chloride to the 1,2-bisi