Addition of Grignard Reagents to Chiral
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Sylvain Roland; Pierre Mangeney
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Article
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2000
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John Wiley and Sons
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English
โ 290 KB
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3,2-b]benzopyran-2-ones / (E)-2-NonenalAsymmetric synthesis / Grignard reactions / Dynamic kinetic resolution / Chiral bisimines / Unsymmetrical 1,2-diamines A diastereoselective synthesis of tert-butyl-1,2-diamines has been developed from the addition of tert-butylmagnesium chloride to the 1,2-bisi