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ChemInform Abstract: Adaptative Biaryl Phosphite—Oxazole and Phosphite—Thiazole Ligands for Asymmetric Ir-Catalyzed Hydrogenation of Alkenes.

✍ Scribed by Javier Mazuela; Alexander Paptchikhine; Oscar Pamies; Pher G. Andersson; Montserrat Dieguez

Publisher
John Wiley and Sons
Year
2010
Weight
71 KB
Volume
41
Category
Article
ISSN
0931-7597

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Adaptative Biaryl Phosphite–Oxazole and
Adaptative Biaryl Phosphite–Oxazole and Phosphite–Thiazole Ligands for Asymmetric Ir-Catalyzed Hydrogenation of Alkenes
✍ Javier Mazuela; Alexander Paptchikhine; Oscar Pàmies; Pher G. Andersson; Montser 📂 Article 📅 2010 🏛 John Wiley and Sons 🌐 English ⚖ 277 KB 👁 1 views

## Abstract A library of readily available phosphite–oxazole/thiazole ligands (**L1 a**–**g**–**L7 a**–**g**) was applied in the Ir‐catalyzed asymmetric hydrogenation of several largely unfunctionalized __E__‐ and __Z__‐trisubstituted and 1,1‐disubstituted terminal alkenes. The ability of the catal