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ChemInform Abstract: Acylphosphonamidates and α-Hydroxyiminophosphonamidates. Synthesis of N-Acylphosphordiamidates by Beckmann Rearrangement. Crystal Structure of (E)-α-Hydroxyiminobenzyl-1- pyrrolidinylphosphinate.

✍ Scribed by E. BREUER; H. ZAHER; Z. TASHMA; D. GIBSON


Publisher
John Wiley and Sons
Year
2010
Weight
34 KB
Volume
28
Category
Article
ISSN
0931-7597

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Acylphosphonamidates and α-hydroxyiminop
✍ Eli Breuer; Hisham Zaher; Zeev Tashma; Dan Gibson 📂 Article 📅 1996 🏛 John Wiley and Sons 🌐 English ⚖ 544 KB

Reaction of methyl benzoylphosphonochloridate (3) with a secondary or primary series of amines yielded methyl benzoylphosphonamidates, 4a-e. The latter compounds reacted with hydroxylamine to yield a-hydroxyiminobenzylphosphonamidates (Sa-e), largely as (E)-isomers. The structure of methyl (E)-a-hyd