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ChemInform Abstract: Acylotropic Intramolecular Rearrangements of Keto Enamines of Benzo[b]-Anellated Heterocycles

✍ Scribed by V. I. Minkin; V. A. Bren'; A. D. Dubonosov; A. V. Tsukanov

Book ID
112049025
Publisher
John Wiley and Sons
Year
2012
Weight
18 KB
Volume
43
Category
Article
ISSN
0931-7597

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## Studies on Pyrimidine-Anellated Heterocycles: Synthesis of Pyrrolo [3,2-d]pyrimidines by Amine Oxide Rearrangement. -A number of pyrrolo[3,2-d]pyrimidine derivatives (VII) is synthesized in 90-95% yields from the corresponding uracils in a one-step process by treatment with MCPBA (VI). The C-C