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ChemInform Abstract: Acylation of Phosphoryl- and Thiophosphorylacetonitriles under Phase Transfer Catalysis Conditions and Keto—Enol Tautomerism of Phosphorus-Substituted Acylacetonitriles

✍ Scribed by T. A. MASTRYUKOVA; I. L. ODINETS; O. I. ARTYUSHIN; R. M. KALYANOVA; K. A. LYSSENKO; A. G. MATVEEVA; P. V. PETROVSKII; M. I. KABACHNIK


Publisher
John Wiley and Sons
Year
2010
Weight
26 KB
Volume
29
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Michael Addition of
✍ E. A. TARASENKO; P. MUKHAIIMANA; A. V. TSVETKOV; N. V. LUKASHEV; I. P. BELETSKAY 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 39 KB 👁 2 views

Addition of Phosphorus-Substituted CH-Acids under Phase-Transfer Conditions. -Phosphonoacetic acid (I) is shown to undergo Michael addition to various activated olefins under phase-transfer conditions. 1:1 or 1:2 Adducts are formed depending on the electronic structure of the olefins and the molar