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ChemInform Abstract: Activated Monoorganotins for the Modified Stille Coupling Reaction with Triflates.

✍ Scribed by E. Fouquet; Alain L. Rodriguez

Publisher: John Wiley and Sons
Year: 2010
Weight: 29 KB
Volume: 30
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.199913091

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✦ Synopsis

Activated Monoorganotins for the Modified Stille Coupling Reaction with Triflates. -Reaction of organic halides (I) with Lappert's stannylene (II) generates a solution of the organotins (III). These can be activated by fluoride and coupled with triflates in a Heck-type reaction to yield the desired products such as (V) and (VII).

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