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ChemInform Abstract: Activated Barrier Crossing in Isomerization Reactions

✍ Scribed by Kimihiko Hara; Naoki Ito

Publisher
John Wiley and Sons
Year
2010
Weight
24 KB
Volume
30
Category
Article
ISSN
0931-7597

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Microscopic friction and solvation in ba
Microscopic friction and solvation in barrier crossing: isomerization of stilbene in size-selected hexane clusters
✍ A.A. Heikal; S.H. Chong; J.S. Baskin; A.H. Zewail πŸ“‚ Article πŸ“… 1995 πŸ› Elsevier Science 🌐 English βš– 939 KB

In order to understand the roles of bulk friction and solvation in barrier crossing reactions, here we report our first study of the isomerization rates for a beam of t-stilbene-hexane, clusters, n = 1-5, at excess energies covering the range Ecx = 0-4000 cm-1. We observe that rates measured at exce