ChemInform Abstract: Acid-Catalyzed Rearrangement of α-Hydroxycyclopropylsilanes.
✍ Scribed by K. SAKAGUCHI; M. FUJITA; Y. OHFUNE
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 32 KB
- Volume
- 29
- Category
- Article
- ISSN
- 0931-7597
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Acid-Catalyzed Rearrangement of Caryophyllene Oxide. -The title reaction affords besides the known clovanediol (III) epoxides (II) and (I). The structures of the latter are especially elucidated by NMR methods. Mechanisms are discussed. -(TSUI, W.-Y.;