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ChemInform Abstract: A Versatile Approach to 2-Substituted 3-Trifluoromethyl-1,3-diols Based on the Reaction of Trifluoroacetaldehyde Ethyl Hemiacetal with Enamines Derived from Aldehydes.

✍ Scribed by Kazumasa Funabiki; Yudai Furuno; Fumiaki Sato; Hiroshi Gonda; Yasuhiro Kubota; Masaki Matsui

Publisher
John Wiley and Sons
Year
2010
Weight
79 KB
Volume
41
Category
Article
ISSN
0931-7597

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✦ Synopsis

Abstract

The reaction of enamine (I) with ethyl hemiacetal (II) followed by acid hydrolysis and subsequent reduction of the intermediate aldehyde gives rise to the diastereomeric mixture of diols (III) and (IV).

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