✦ LIBER ✦
ChemInform Abstract: A Traceless, One-Pot Preparation of Unsymmetric Disulfides from Symmetric Disulfides Through a Repeated Process Involving Sulfenic Acid and Thiosulfinate Intermediates.
✍ Scribed by Minsoo Han; Jong Tak Lee; Hoh-Gyu Hahn
- Publisher
- John Wiley and Sons
- Year
- 2011
- Weight
- 25 KB
- Volume
- 42
- Category
- Article
- ISSN
- 0931-7597
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✦ Synopsis
Abstract
The reaction of symmetric disulfides (I) with sulfuryl chloride gives sulfenyl chlorides, which are directly coupled with thiols (II) in the presence of water to yield unsymmetrical disulfides (III).