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ChemInform Abstract: A Three-Component One-Pot Synthesis of Functionalized 5,5-Dicyanocyclopenta-1,3-dienes from Arylidenemalononitriles, Activated Acetylenes, and KCN or KSCN.

✍ Scribed by Issa Yavari; Mehdi Sirouspour; Sanaz Souri


Publisher
John Wiley and Sons
Year
2011
Weight
26 KB
Volume
42
Category
Article
ISSN
0931-7597

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A Three-Component One-Pot Synthesis of F
✍ Issa Yavari; Mehdi Sirouspour; Sanaz Souri 📂 Article 📅 2010 🏛 John Wiley and Sons 🌐 German ⚖ 167 KB

## Abstract The reaction of dialkyl acetylenedicarboxylates with arylidenemalononitriles in the presence of KSCN in MeCN led to a mixture of dialkyl (3__E__)‐4‐aryl‐3‐(arylideneamino)‐5,5‐dicyanocyclopenta‐1,3‐diene‐1,2‐dicarboxylates and dialkyl 4‐aryl‐5‐cyanothiophene‐2,3‐dicarboxylates. When the