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ChemInform Abstract: A Tandem Amination/Lactamization Route to 2-Azabicyclo[2.2.2]octanones.

✍ Scribed by James D. Cuthbertson; Andrew A. Godfrey; Richard J. K. Taylor


Publisher
John Wiley and Sons
Year
2011
Weight
32 KB
Volume
42
Category
Article
ISSN
0931-7597

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✦ Synopsis


Abstract

The reaction can be extended to the synthesis of N‐substituted derivatives.


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ChemInform Abstract: A Stereoselective,
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A Stereoselective, Tandem [2 + 2] Photocycloaddition-Hydrolysis Route to Aldol-Type Adducts. -The photocycloaddition of aromatic aldehydes (I) with cyclic ketene silyl acetals (II) or (V) proceeds regio-and stereoselectively to afford predominantly bicyclic oxetanes [cf. (III)] having exo-configura