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ChemInform Abstract: A Synthetic Approach to Perhydro-3-isoquinolinones Bearing an Angular Methyl Group via Organocuprate Addition.

✍ Scribed by Peter Stanetty; M. Hassan Bahardoust; Marko D. Mihovilovic; Kurt Mereiter


Publisher
John Wiley and Sons
Year
2010
Weight
30 KB
Volume
31
Category
Article
ISSN
0931-7597

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ChemInform Abstract: A Novel Hetero-Diel
✍ P. STANETTY; M. D. MIHOVILOVIC; K. MEREITER; H. VOELLENKLE; F. RENZ 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 33 KB 👁 1 views

The title compounds (III), (IV), and (VI) are synthesized by a hetero-Diels-Alder reaction using the sterically demanding diene (I) as a new building block. The effect of commonly used Lewis acids and the substitution pattern of various imines (II) on both the mechanism and the diastereoselectivity