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ChemInform Abstract: A Synthesis of (E)-(1-Organo-1-alkenyl)boronates by the Palladium- Catalyzed Cross-Coupling Reaction of (E)-1,2-Bis(boryl)-1-alkenes with Organic Halides: A Formal Carboboration of Alkynes via the Diboration- Coupling Sequence.

โœ Scribed by T. ISHIYAMA; M. YAMAMOTO; N. MIYAURA

Book ID
112042365
Publisher
John Wiley and Sons
Year
2010
Weight
33 KB
Volume
28
Category
Article
ISSN
0931-7597

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๐Ÿ“œ SIMILAR VOLUMES

A stereoselective route to alkenyl sulfi
A stereoselective route to alkenyl sulfides through the palladium-catalyzed cross-coupling reaction of 9-alkyl-BBN with 1-bromo-1-phenylthioethene or (E)- and (Z)-2-bromo-1-phenylthio-1-alkenes
โœ Yukio Hoshino; Tatsuo Ishiyama; Norio Miyaura; Akira Suzuki ๐Ÿ“‚ Article ๐Ÿ“… 1988 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 247 KB

The reaction of 9-alkyl-9-BBNs with 1-bromo-i-phenylthioethene or (E)-and (Z)-2-bromo-lphenylthio-1-alkenes takes place readily in the presence of Pd(PPh& and sodium hydroxide to afford stereodefmed vinylic sulfides in excellent yields.