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ChemInform Abstract: A Suzuki Coupling Approach to Bufadienolides.

✍ Scribed by Edward C. Gravett; Philip J. Hilton; Keith Jones; Fernando Romero

Publisher
John Wiley and Sons
Year
2010
Weight
27 KB
Volume
33
Category
Article
ISSN
0931-7597

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A Suzuki Coupling Approach to Trifluoromethyl Derivative of Targretin ( LGD 1069). -Key step in the synthesis of the title compound (IX) is the palladium catalyzed cross-coupling reaction of the arylboronic acid (VI) with the vinyl triflate (VII). -(QING, F.