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ChemInform Abstract: A Simple Route to 4-Aryl and 4-Hetaryl Substituted 6-Methyl-2,2-difluoro-1,3,2-(2H)-dioxaborines.

✍ Scribed by Gunter Goerlitz; Horst Hartmann; Bernhard Nuber; J. Jens Wolff


Publisher
John Wiley and Sons
Year
2010
Weight
31 KB
Volume
30
Category
Article
ISSN
0931-7597

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On the formation and solvolysis of 4-ary
✍ Gunter GΓΆrlitz; Horst Hartmann πŸ“‚ Article πŸ“… 1997 πŸ› John Wiley and Sons 🌐 English βš– 209 KB πŸ‘ 1 views

The condensation of aryl methyl ketones 6 with acetic anhydride 4a in the presence of the boron trifluorideacetic acid adduct 7 gives rise to the formation of 4aryl-2,2-difluoro-6-methyl-1,3,2-(2H)-dioxaborines 8 in satisfactory yields. The stable 4-aryl-2,2-difluoro-6methyl-1,3,2-(2H)-dioxaborines