ChemInform Abstract: A Simple Copper Catalyst for Both Aziridination of Alkenes and Amination of Activated Hydrocarbons with Chloramine-T Trihydrate.
✍ Scribed by David P. Albone; Pavandeep S. Aujla; Paul C. Taylor; Stephen Challenger; Andrew M. Derrick
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 29 KB
- Volume
- 30
- Category
- Article
- ISSN
- 0931-7597
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✦ Synopsis
A Simple Copper Catalyst for Both Aziridination of Alkenes and Amination of Activated Hydrocarbons with Chloramine-T Trihydrate.
-A new procedure for the nitrene-transfer aziridination of aryl alkenes (I) and (IV) leading to formation of the corresponding aziridines (III) and (V) is reported. p-Toluenesulfonamide is formed as the main by-product. Under the same reaction conditions the amination reaction of tetralin (VI) provides p-toluenesulfonamide as major product and a reasonable amount of the target amination product (VII). -(ALBONE, DAVID P.; AUJLA, PAVANDEEP S.;