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ChemInform Abstract: A Short Synthesis of 6,9-Desmethyldeoxoartemisinin and Its Isomer.

โœ Scribed by C. H. OH; J. H. KANG; G. H. POSNER

Publisher
John Wiley and Sons
Year
2010
Weight
28 KB
Volume
28
Category
Article
ISSN
0931-7597

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9-(ฮฒ-Pyridylmethylidene)-4-azafluorene. Synthesis of Z-and E-Isomers of Its Iodomethylate and Reduction of the Z-Isomer. -Reaction of azafluorene (I) with formylpyridine (II) affords an inseparable 1:1 mixture of E-and Z-isomers of pyridylmethylideneazafluorene (III). In contrast, the E-and Z-isom