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ChemInform Abstract: A Regio- and Diastereoselective Platinum-Catalyzed Tandem [2 + 1]/[3 + 2] Cycloaddition Sequence.

✍ Scribed by Thierry Achard; Aymeric Lepronier; Yves Gimbert; Herve Clavier; Laurent Giordano; Alphonse Tenaglia; Gerard Buono

Publisher
John Wiley and Sons
Year
2011
Weight
51 KB
Volume
42
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Highly Regio- and D
ChemInform Abstract: Highly Regio- and Diastereoselective Anionic [3 + 2] Cycloaddition under Phase Transfer Catalytic Conditions.
✍ Vincent Gembus; Svetlana Postikova; Vincent Levacher; Jean-Francois Briere πŸ“‚ Article πŸ“… 2011 πŸ› John Wiley and Sons βš– 36 KB

## Abstract In the presence of AMI, the allylic sulfones (Ia) and (IV) undergo highly regio‐ and diastereoselective [3 + 2] cycloaddition with enones to afford trans‐substituted cyclopentenes of type (III)/(VI).