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ChemInform Abstract: A Palladium(0)-Mediated Approach to Some Novel C-4-Substituted Neu5Ac2en Derivatives.

✍ Scribed by G. B. KOK; M. VON ITZSTEIN

Publisher: John Wiley and Sons
Year: 2010
Weight: 31 KB
Volume: 29
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.199827260

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✦ Synopsis

A Palladium(0)-Mediated Approach to Some Novel C-4-Substituted Neu5Ac2en Derivatives.

-A range of novel C-4-modified 2,3unsaturated N-acetylneuraminic acid analogues [cf. (III), (V)] are prepared via Pd(0)-catalyzed cross-coupling between 4-chloro-4-deoxy-N-acetylneuraminic acids and organostannanes. The reactions proceed with complete regio-and stereocontrol. -(KOK, G.

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