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ChemInform Abstract: A Palladium-Catalyzed Carbonylative Route to Primary Amides.

✍ Scribed by E. MORERA; G. ORTAR

Publisher
John Wiley and Sons
Year
2010
Weight
35 KB
Volume
29
Category
Article
ISSN
0931-7597

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✦ Synopsis

1998 carboxylic amides

carboxylic amides (benzene compounds) Q 0490

30 -101

A Palladium-Catalyzed Carbonylative Route to Primary Amides.

-The Pd-catalyzed carbonylation of various aryl and vinyl iodides and triflates with carbon monoxide in the presence of hexamethyldisilazane yields the corresponding carbonic amides after acidic hydrolysis. Optimized reaction conditions allow the application of the mild and efficient procedure to a broad spectrum of substrates. -(MORERA, E.;

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