Application of Copper Catalysis in a One-Pot Procedure for 1-Alkyl-3-methoxy-2-methylthiopyrroles Starting from Methoxyallene and Alkyl Isothiocyanates. -Usual workup of a reaction mixture obtained from lithiation of methoxyallene (I), followed by addition of thiocyanates and methyl iodide affords
✦ LIBER ✦
ChemInform Abstract: A One-Step Procedure for Facile Preparation of D-Glucopyranosides with a Free 2-OH from O-Peracetylated β-D-Glucopyranose.
✍ Scribed by M.-Z. LIU; H.-N. FAN; Z.-W. GUO; Y.-Z. HUI
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 35 KB
- Volume
- 28
- Category
- Article
- ISSN
- 0931-7597
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✦ Synopsis
A One-Step Procedure for Facile Preparation of D-Glucopyranosides with a Free 2-OH from O-Peracetylated β-D-Glucopyranose. -Various β-D-glucopyranosides with a free hydroxyl group on C-2 ( III) are prepared in a one-step procedure from O-peracetylated glucopyranose and applied to the synthesis of Glc 1 → 2 linked disaccharides (cf. (VIII)). -(LIU,
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