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ChemInform Abstract: A One-Pot Stereoselective Synthesis of Hydroxy-ketenedithioacetals from Aldehydes.

✍ Scribed by S. TCHERTCHIAN; Y. VALLEE


Book ID
112023740
Publisher
John Wiley and Sons
Year
2010
Weight
28 KB
Volume
26
Category
Article
ISSN
0931-7597

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The reaction of Garner's aldehyde with dithioacetate enethiolates followed by alkylation of the intermediate aldolate gives hydroxy-ketenedithioacetals with a moderate anti selectivity. This methodology was applied to the synthesis of various other ketene dithioacetals with high E or Z stereoselecti

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## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a β€œFull Text” option. The original article is trackable v