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ChemInform Abstract: A One-Flask Synthesis of Dihydronaphthalenemethanols by Directed Addition of Organolithium Reagents to BHA Naphthalenecarboxylates.

✍ Scribed by Mitsuru Shindo; Kenji Koga; Yasutomi Asano; Kiyoshi Tomioka

Publisher: John Wiley and Sons
Year: 2010
Weight: 33 KB
Volume: 30
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.199935115

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✦ Synopsis

A One-Flask Synthesis of Dihydronaphthalenemethanols by Directed Addition of Organolithium Reagents to BHA Naphthalenecarboxylates.

-A stereoselective one-pot synthesis of the title compounds is developed based on the directed addition of organolithium reagents to di-tert-butylated hydroxy anisole (BHA) naphthalene carboxylates (I) and (V), providing a useful alternative to other protocols. -(SHINDO, MITSURU;

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