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ChemInform Abstract: A Novel Simple Synthesis of Bis(diorganoselenophosphoryl)selenides (R2PSe)2Se from Secondary Phosphines and Elemental Selenium.

✍ Scribed by Alexander V. Artem'ev; Nina K. Gusarova; Svetlana F. Malysheva; Igor A. Ushakov; Boris A. Trofimov

Publisher: John Wiley and Sons
Year: 2010
Weight: 23 KB
Volume: 41
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.201032184

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✦ Synopsis

Abstract

An unexpected reaction of secondary phosphines with excess elemental selenium affords the title compounds (II) in good yields.The expected diselenide products and diselenophosphinoic acids are not observed.

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