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ChemInform Abstract: A Novel Route to Disubstituted (7)Thiaheterohelicene via Biaryl- and Carbonyl-Coupling Reactions.

✍ Scribed by K. TANAKA; H. SUZUKI; H. OSUGA

Publisher
John Wiley and Sons
Year
2010
Weight
31 KB
Volume
28
Category
Article
ISSN
0931-7597

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✦ Synopsis

A Novel Route to Disubstituted (7)Thiaheterohelicene via Biaryland Carbonyl-Coupling Reactions.

-The key steps in the new nonphotochemical synthesis of the title compound (XI) are the palladium-catalyzed cross-coupling reaction between (VI) and (VIII) and the following intramolecular McMurry coupling reaction of the dialdehyde (X). -(TANAKA, K.; SUZUKI,

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