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ChemInform Abstract: A Novel Oxidative Cyclization onto Vinyl Silanes.

✍ Scribed by Timothy J. Donohoe; Paul C. M. Winship; Ben S. Pilgrim; Daryl S. Walter; Cedric K. A. Callens

Publisher: John Wiley and Sons
Year: 2011
Weight: 55 KB
Volume: 42
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.201107136

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✦ Synopsis

Abstract

A variety of tetrahydrofurans bearing a silyl group at the ring junction is prepared in good yields stereoselectively via a osmium‐catalyzed oxidative cyclization of appropriate terminal vinyl silanes.

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