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ChemInform Abstract: A Novel One-Pot Synthesis of Homochiral (R)-(-)- and (S)-(+)-Fe(CO)(. eta.5-C5H5)(PPh3)COCH3.

โœ Scribed by S. J. COOK; J. F. COSTELLO; S. G. DAVIES; H. T. KRUK


Book ID
112021231
Publisher
John Wiley and Sons
Year
2010
Weight
27 KB
Volume
26
Category
Article
ISSN
0931-7597

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Application of the iron acyl complex R-(
โœ Stephen G. Davies; David Middlemiss; Alan Naylor; Martin Wills ๐Ÿ“‚ Article ๐Ÿ“… 1989 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 307 KB

## Surnmnry: The enantiomerically pure iron acyl complex R-(-)-[($-CSH5)Fe(CO)(PPh3)-CUCH20({lR,2S,5R]menthyl))] tepresents a source of homochiral formyl anion equivalent applicable to the synthesis of enantiomerkally pare a-hydroxy acetals from aldehydes. The formyl anion or a synthetic equivale