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ChemInform Abstract: A Novel Method for Stereoselective Glycosidation with Thioglycosides: Promotion by Hypervalent Iodine Reagents Prepared from PhIO and Various Acids.

โœ Scribed by K. FUKASE; I. KINOSHITA; T. KANOH; Y. NAKAI; A. HASUOKA; S. KUSUMOTO


Book ID
112034447
Publisher
John Wiley and Sons
Year
2010
Weight
36 KB
Volume
27
Category
Article
ISSN
0931-7597

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A novel method for stereoselective glyco
โœ Koichi Fukase; Ikuko Kinoshita; Takeshi Kanoh; Yoshihiko Nakai; Atsushi Hasuoka; ๐Ÿ“‚ Article ๐Ÿ“… 1996 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 472 KB

Combinations of iodosobenzene (PhlO) and various acids effectively promote glycosidafion using thioglycosides as glycosyl donors. 13-Selective glucosidation was effected by use of TfOH, Tf20, TMSOTf, Sn(OTf)2, and Yb(OTf) 3 as catalysts with 2-O-benzoylawxl or 2-0benzylated donors by virtue of eithe