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ChemInform Abstract: A Novel Highly Stereoselective Synthesis of Chiral 5- and 4,5-Substituted 2-Oxazolidinones.

โœ Scribed by M. Bertau; M. Buerli; E. Hungerbuehler; P. Wagner


Publisher
John Wiley and Sons
Year
2010
Weight
36 KB
Volume
33
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Stereoselective Met
โœ A. M. Shestopalov; K. G. Nikishin ๐Ÿ“‚ Article ๐Ÿ“… 2010 ๐Ÿ› John Wiley and Sons โš– 27 KB ๐Ÿ‘ 2 views

Stereoselective Method of Synthesis of Substituted trans-4,5-Dihydro-2-aminothiophenes. -Reaction of alkyl 2-cyano-4-benzoylbutanoate (I) with sulfur in the presence of base affords the title dihydrothiophene derivatives (II). In this case, the electron-accepting benzoyl group (instead of the CN gr