A novel chiral phosphinediamine ligand (PN 2) was prepared from (S)-Iphenylethylamine and dichloroisopropylphosphine. The rhodium-PN 2 catalyst utilizing selective ligation of the amino unit and electrostatic interaction between the ligand and a substrate gave high enantioselectivities up to 92% ee
β¦ LIBER β¦
ChemInform Abstract: A Novel Chiral Phosphinediamine Ligand and Asymmetric Hydrogenation of Acrylic Acid Derivatives.
β Scribed by I. YAMADA; M. YAMAGUCHI; T. YAMAGISHI
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 28 KB
- Volume
- 28
- Category
- Article
- ISSN
- 0931-7597
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