ChemInform Abstract: A Novel and Flexible Synthesis of Pyranose Spiroacetal Derivatives.

✍ Scribed by P. A. V. VAN HOOFT; M. A. LEEUWENBURGH; H. S. OVERKLEEFT; G. A. VAN DER MAREL; C. A. A. VAN BOECKEL; J. H. VAN BOOM

• Publisher: John Wiley and Sons
• Year: 2010
• Weight: 30 KB
• Volume: 29
• Category: Article
• ISSN: 0931-7597
• DOI: 10.1002/chin.199844212

✦ Synopsis

1998 carbohydrates carbohydrates U 0500 44 -212 A Novel and Flexible Synthesis of Pyranose Spiroacetal Derivatives. -Pyranose based spiroacetals (IV) are conveniently obtained by montmorillonite K-10 mediated glucosidation of perbenzylated Grignard adducts [cf. (I)] followed by ring-closing metathesis. -(VAN HOOFT, P. A. V.;