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ChemInform Abstract: A Novel and Expeditious Approach to Symmetrical and Unsymmetrical 5,5-Spiroimide Building Blocks

✍ Scribed by Iyad Allous; Sebastien Comesse; Adam Daich

Publisher: John Wiley and Sons
Year: 2008
Weight: 39 KB
Volume: 39
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.200828113

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## Abstract The enantiopure epoxides 2–6 were synthesized from 1,2;5,6‐di‐O‐isopropylidene‐D‐mannitol (1). The terminal epoxides 2 and 3 are available from the desoxy mannitol 9 in three steps. The __C__~2~‐symmetrical epoxides 4 and 5 were generated via the C‐4‐inverted alcohol 15. The __C__~2~‐sy