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ChemInform Abstract: A Novel and Efficient Method for the Synthesis of Tetrahydropyranyl Ethers Catalyzed by Sc(OTf)3.

✍ Scribed by Tsutomu Watahiki; Hisashi Kikumoto; Masaya Matsuzaki; Takeshi Suzuki; Takeshi Oriyama

Publisher: John Wiley and Sons
Year: 2010
Weight: 31 KB
Volume: 33
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.200224071

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A Mild and Efficient Method for Converting Alcohols and Tetrahydropyranyl Ethers to Bromides with Inversion of Configuration. - Adding 2,4,4,5-cyclohexadienone to triphenylphosphine generates a bromotriphenylphosphonium salt which is a powerful brominating reagent for the conversion of alcohols or