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ChemInform Abstract: A Nitro Sugar Derivative Route to 2-Thioepisophorose and 2- Thiosophorose and Their Remarkable Facile Epimerization.

✍ Scribed by M. PETRUSOVA; E. LATTOVA; M. MATULOVA; L. PETRUS; J. N. BEMILLER

Book ID
112035118
Publisher
John Wiley and Sons
Year
2010
Weight
31 KB
Volume
27
Category
Article
ISSN
0931-7597

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A nitro sugar derivative route to 2-thio
A nitro sugar derivative route to 2-thioepisophorose and 2-thiosophorose and their remarkable facile epimerization
✍ Mária Petrušová; Erika Lattová; Mária Matulová; Ladislav Petruš; James N. BeMill 📂 Article 📅 1996 🏛 Elsevier Science 🌐 English ⚖ 552 KB

The addition of 1-thio-D-glucose sodium salt to per-O-acetylated 1,2-dideoxy-1-nitro-D-arabino-hex-1-enitol, readily available from D-arabinose, afforded the corresponding 2-S-glycosylated 1-deoxy-1-nitro-D-mannitol and -D-glucitol peracetates. These, after deacetylation, were transformed by the Nef